Complex Ni-(S)BPB-Gly

(S)-[O-[(N-Benzylprolyl)amino](phenyl)methyleneiminoacetate(2-)-N,N',N''-nickel(II) C27H25N3NiO3 F.W. 498.2 CAS [96293-19-5] Ni-(S)-BPB-Gly complex was first used for the synthesis of beta-hydroxy-alpha -amino acids but later employed with great success in the synthesis (S)-alpha-amino acids.
Y.N. Belokon, V.I. Bakhmutov, N.I. Chemoglazova, K.A. Kochetkov, S.V. Vitt, N.S. Garbalinskaya, and V.M. Belikov. J. Chem. Soc., Perkin Trans. I, 30531 2 (1 988). Y.N. Belokon, AS. Sagyan, S.A Djamgaryan, V.I. Baichmutov, and V.M. Belikov. Tetrahedron 44, 5507-551 4 (1 988). Y.N. Belokon, AS. Sagyan, S.A. Djamgaryan, V.I. Bakhrnutov, S.V. Vitt, AS. Batsanov, Y.T. Stnichkov, and V.M. Belikov. J. Chem. Soc., Perkin Trans. 1 2301 -231 0 (1 990). Y.N. Belokon, AN. Popkov, N.I. Chemoglazova, M.B. Saporovskaya, V.I. Bauhmutov, and V.M. Belikov. Chem. Comm. 1336-1 337 (1 988). Y.N. Belokon, I.E. Zel'Tzer, V.I. Bakhmutov, M.B. Saporovskaya, M.G. Ryzhov, Al. Yanovsky, Y.T. Struchkov, and V.M. Belikov. J. Am. Chem. Soc. 105, 201 0-201 7 (1 983). Y.N. Belokon. Pure and Applied Chemistry 64, 191 7-1 924 (1 992). V.A Soloshonok, D.V. Avilov, V.P. Kukhar, V.I. Tararov, K.A. Kochetkov, T.F. Savel'eva, T.D. Churkina, N.S. Ikonnikov, S.A Orlova, AP. Pysarevsky, Y.T. Stnichkov, N. I. Raevsky, and Y.N. Belokon. Tetrahedron: Asyrnmetry 6, 1 741 4756 (1 995). V.A Soloshonok, D.V. Avilov, and V.P. Kukhar. Tetrahedron: Asymrnetry 7, 1 547-1 550 (1 996). V.A. Soloshonok, D.V. Avilov, and V.P. Kukhar. Tetrahedron 52, 12433-12442 (1 996). C.W.G. Fishwick, J.M. Sanderson, and J.B.C. Findlay. Tetrahedron Lett. 35, 461 1-461 4 (1 994). KJ. Fasth and B. Langstrom. Acta Chem. Scand. 44, 720-725 (1990).

(S)-[O-[(N-Benzylprolyl)amino](phenyl)methyleneiminoacetate(2-)-N,N',N''-nickel(II)

C27H25N3NiO3
F.W. 498.2
CAS [96293-19-5]

Ni-(S)-BPB-Gly complex was first used for the synthesis of beta-hydroxy-alpha -amino acids but later employed with great success in the synthesis (S)-alpha-amino acids.

Y.N. Belokon, V.I. Bakhmutov, N.I. Chemoglazova, K.A. Kochetkov, S.V. Vitt, N.S. Garbalinskaya, and V.M. Belikov. J. Chem. Soc., Perkin Trans. I, 30531 2 (1 988).
Y.N. Belokon, AS. Sagyan, S.A Djamgaryan, V.I. Baichmutov, and V.M. Belikov. Tetrahedron 44, 5507-551 4 (1 988).
Y.N. Belokon, AS. Sagyan, S.A. Djamgaryan, V.I. Bakhrnutov, S.V. Vitt, AS. Batsanov, Y.T. Stnichkov, and V.M. Belikov. J. Chem. Soc., Perkin Trans. 1 2301 -231 0 (1 990).
Y.N. Belokon, AN. Popkov, N.I. Chemoglazova, M.B. Saporovskaya, V.I. Bauhmutov, and V.M. Belikov. Chem. Comm. 1336-1 337 (1 988).
Y.N. Belokon, I.E. Zel'Tzer, V.I. Bakhmutov, M.B. Saporovskaya, M.G. Ryzhov, Al. Yanovsky, Y.T. Struchkov, and V.M. Belikov. J. Am. Chem. Soc. 105, 201 0-201 7 (1 983).
Y.N. Belokon. Pure and Applied Chemistry 64, 191 7-1 924 (1 992).
V.A Soloshonok, D.V. Avilov, V.P. Kukhar, V.I. Tararov, K.A. Kochetkov, T.F. Savel'eva, T.D. Churkina, N.S. Ikonnikov, S.A Orlova, AP. Pysarevsky, Y.T. Stnichkov, N. I. Raevsky, and Y.N. Belokon. Tetrahedron: Asyrnmetry 6, 1 741 4756 (1 995).
V.A Soloshonok, D.V. Avilov, and V.P. Kukhar. Tetrahedron: Asymrnetry 7, 1 547-1 550 (1 996).
V.A. Soloshonok, D.V. Avilov, and V.P. Kukhar. Tetrahedron 52, 12433-12442 (1 996).
C.W.G. Fishwick, J.M. Sanderson, and J.B.C. Findlay. Tetrahedron Lett. 35, 461 1-461 4 (1 994).
KJ. Fasth and B. Langstrom. Acta Chem. Scand. 44, 720-725 (1990).